In a study published in the journal Nature Synthesis, a research team led by Professor Ken Tanaka from Tokyo Institute of Technology developed a rhodium (Rh)-catalyzed enantioselective [2+2+1] ...

X for H, MeO, etc. (a) Reaction conditions and (b) Representative reaction scope. Figure 4. Enantioselective decarboxylative alkylation. (a) Reaction conditions and (b) Representative reaction scope.

1 Department of Chemistry and Biochemistry, University of Massachusetts Dartmouth, North Dartmouth, USA. 2 Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, USA.

Here, we show that the synergistic merger of three catalytic processes—photoredox, enamine and hydrogen-atom transfer (HAT) catalysis—enables an enantioselective α-aldehyde alkylation ...

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In summary, we have reported the first method for catalytic enantioselective alkylation of monocyclic 5-, 6- and 7-membered lactam enolate derivatives to form α-quaternary and α-tetrasubstituted ...

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